Reposition Toolbar Buttons
If you want to rearrange any of the icons on your Explorer Windows toolbar, do the following open explorer with any open folder window, select View, Toolbars, Customize. Under Current Toolbar Buttons, select a button you'd like to move, then click the Move Up or Move Down buttons as necessary. Repeat these steps for any other buttons you want to reposition, then click Close. This means that you can move your icons to how you want them.